Journal of Chemical Physics, Vol.104, No.12, 4406-4410, 1996
Resonance-Enhanced Multiphoton Ionization Spectroscopy of the Snf Radical
The resonance enhanced multiphoton ionization spectrum of the free radical SnF has been recorded using excitation wavelengths in the range 540 to 360 nm. The previously documented C2 Delta, D, E(2)II, and F-2 Sigma(+) states and two hitherto unidentified excited states, the H and I-2 Phi, states, were all observed as two-photon resonances. Band contour simulations yielded spectroscopic constants for the E, F, and I states.