Journal of the Korean Industrial and Engineering Chemistry, Vol.10, No.1, 148-153, February, 1999
PMMA 용액에서 중합된 TLCP in situ 복합재료에 관한 연구
On the In situ Composites Containing TLCP Polymerized in PMMA Solution
초록
2-bromoterephthaloyl chloride와 1,4-bis(p-hydroxybenzoyloxy)butane을 PMMA 용액내에서 중축합시켜 insitu 복합재료를 제조하였다. 이들의 합성확인 및 열적, 기계적 성질은 FT-IR, FT-NMR, DSC와 DMTA에 의해서, 몰폴로지는 광학현미경과 SEM을 사용하여 조사하였다. 합성된 TLCP는 네마틱상을 보였고, 복합재료내 PMMA의 유리전이온도와 기계적 성질은 TLCP의 농도증가와 함께 증가하였다. TLCP domain은 PMMA 매트릭스내에서 미세 분산되었음을 확인하였고 in situ 중합에 의해 제조된 20 wt% TLCP/PMMA 복합재료는 같은 조성의 용액 블렌딩에 의해서 제조된 재료보다 더 높은 기계적 강도와 미세 분산도를 보였다.
In situ composites containing a thermotropic liquid crystalline polymer were prepared by polycondensation of 1,4-bis(p-hydroxy-benzoyloxy)butane with 2-bromoterephthaloyl chloride in a poly(methyl methacrylate) solution. Morphology and mechanical, thermal properties of the composites were examined by differential scanning calorimeter(DSC), dynamic mechanical thermal analyser(DMTA), optical microscope and scanning electron microscope(SEM). The TLCP domains showed nematic phase. The glass transition temperature(Tg) and mechanical properties of the PMMA in the composites increased with increasing the content of TLCP. The TLCP domains were finely dispersed in the PMMA matrix. The 20 wt% TLCP/PMMA composite prepared by in situ polymerization showed more improved mechanical property with finely well dispersed morphology compared with that prepared by solution blending of the same composition.
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