A novel electrochemically driven process (E-peroxone) was employed to treat landfill leachate concentrates that were generated from reverse osmosis of biologically pretreated leachate. In the E-peroxone system, O-3 was produced from O-2 using an ozone generator. The O-2 and O-3 gas mixture from the ozone generator was then sparged into a reactor that had a carbon-polytetrafluorethylene (carbon-PTFE) cathode, which can convert O-2 to H2O2 effectively. The in situ generated H2O2 then reacted with the sparged O-3 to produce a very powerful oxidant (OH)-O-center dot, thus achieving synergy of O-3 and H2O2 (i.e., peroxone) on organic pollutant degradation. Up to 87% of the total organic carbon (TOC) was removed from the leachate concentrates after 4 h of the E-peroxone process. In comparison, ozonation, conventional peroxone (using externally added H2O2), and electro-Fenton treatment removed only 45%, 65%, and 71% TOC, respectively, under similar reaction conditions in 4h. The results indicate that the E-peroxone process may provide a convenient and effective alternative to conventional advanced oxidation processes for degrading refractory organic pollutants in wastewater. (c) 2013 Elsevier Ltd. All rights reserved.