Electrochimica Acta, Vol.102, 306-311, 2013
Watermelon used as a novel carbon source to improve the rate performance of iron oxide electrodes for lithium ion batteries
The pulp of a watermelon consists of watermelon juice and flesh wall. After a hydrothermal process at 160 degrees C, the pulp turns into a carbon-based composite powder composed of micrometer particles and nanosheets (CPs-CSs). Through a similar hydrothermal process with the mixture of watermelon pulp and an ethanolic solution of ferric nitrate as the precursors, a powder of iron oxide-CPs-CSs composite is also synthesized. X-ray diffraction, scanning and transmission electron microscopies and BET surface area measurement are employed to study the compositions and structures of these composite powders. Their electrochemical properties as potential anode materials of lithium ion batteries are also investigated. It is found that after a heat treatment at 700 degrees C and 800 degrees C, the CPs-CSs composites are mesoporous carbon materials with a specific surface area of 898 m(2) g(-1) and 452 m(2) g(-1), respectively. The iron oxide-CPs-CSs composites after a heat treatment at 700 degrees C and 800 degrees C are all Fe3O4-CPs-CS5. When used as anode materials, both CPs-CSs and Fe3O4-CPs-CSs show very good rate performance. Thanks to the higher surface area of the carbon component, the 700 degrees C-treated Fe3O4-CP5-CSs is superior to others in rate capability. It can deliver a discharge capacity of 350 mA hg-1 even at a high current density of 2500 mA g(-1). (c) 2013 Elsevier Ltd. All rights reserved.