A p-n junction of poly (3,4-ethylenedioxythiophene) (PEDOT) - dye-sensitized TiO2 is introduced into the large-area flexible dye-sensitized solar cell (DSSC) as an anode. This p-n junction is fabricated using a cyclic voltamrnetry electropolyrnerization of PEDOT onto a Ti foil substrate, and then treated in the aqueous ammonia, finally subjected to coating TiO2 by a doctor-scraping technique, all of preparations and treatments are carried out under low temperature. The obtained p-n junction forms a single directional pathway for electron transport which benefites the charge separation. The large-area (10 cm(2)) flexible DSSC with the p-n junction demonstrates an enhanced photovoltaic conversion efficiency of up to 6.51% compared to 4.89% for the DSSC without the p-n junction due to its low series resistance and charge-transfer resistance, high effective electron lifetime for recombination. As a result, the DSSC fabricated using the p-n junction can be suitable for high powered DSSC applications. (C) 2013 Elsevier Ltd. All rights reserved.