Electrochimica Acta, Vol.121, 175-182, 2014
Ultralong Rutile TiO2 Nanorod Arrays with Large Surface Area for CdS/CdSe Quantum Dot-sensitized Solar Cells
By using hydrothermal method and post-etched with hydrochloric acid at high temperature, the ultralong TiO2 nanorod arrays (TNARs) for CdS/CdSe co-sensitized solar cells (QDSCs) were fabricated on fluorine-doped tin oxide (FTO) glass. Then CdS quantum dots (QDs) and CdSe QDs were deposited respectively on the as-prepared TNARs by successive ionic layer adsorption reaction (SILAR) and chemical bath deposition (CBD). The deposition time of CdSe and the etching time of TNARs were regulated to optimize the properties of energy conversion. The morphologies, crystal structure and optical prosperities of TNARs/CdS/CdS were characterized by SEM, TEM, XRD, EIS and UV-vis spectra. A thickness of 17.6 mu m TNARs with large inner surface area was first used for sandwich-type ordered QDSCs, it is found that the J(sc) reached the maximum value (17.22 mA cm(-2)) and the cell conversion efficiency obtained with Pt as counter electrode reached 2.66%. (C) 2014 Elsevier Ltd. All rights reserved.