The effect of temperature on the electrochemical behaviour of reinforced mortar samples contaminated with chlorides was investigated using EIS. The results show an exponential dependence of the mortar cover resistivity with the temperature. This dependency was interpreted as being due to electrostatic interaction between moving ions and charged pore walls, at the gel level structure. The corrosion rate showed a complex dependency with temperature. The Eyring equation explained the behaviour, with distinct reaction paths above and below about 30 degrees C, the temperature at which the electrolyte reached a pH of 12. In the presence of chlorides, the pH was lower for a given temperature. (C) 2013 Elsevier Ltd. All rights reserved.