Graphene nanosheet (GNS) has a remarkably high ratio of surface area to thickness and intense inter-sheet aggregation, which heavily resist mass diffusion in vertical orientation. Here, we establish a fast-speed mass diffusion passage by creating pores in GNS, and the corresponding Pt catalyst (Pt/rPGO) displays 15.5 times mass diffusion rate than that of the pristine GNS supported Pt catalyst (Pt/rGO). Thus, the Pt/rPGO catalyst exhibits 1.5 times increase in Pt mass activity toward oxygen reduction reaction compared with the Pt/rGO. Significantly, after H-2 thermal treatment, the mass activity of the Pt/rPGO further increases to 1.9 times that of the Pt/rGO, and its electrochemical stability is also greatly improved. (C) 2014 Elsevier Ltd. All rights reserved.