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Journal of Chemical Physics, Vol.105, No.12, 5294-5297, 1996
Femtosecond Reaction Dynamics in the Gas-to-Liquid Transition Region - Observation of a 3-Phase Density-Dependence
We report the observation of a striking density dependence in the coherence dynamics of an elementary reaction, solute iodine in solvent rare gases (density from 0 to 50 mol/l). With the help of MD simulations, the time scales of slow and fast solvent-force fluctuations are resolved and the underlying mechanism is revealed.
Keywords:RAMAN GAIN SPECTROSCOPY;COMPUTER-SIMULATIONS;HIGH-PRESSURES;WAVE-PACKET;Q-BRANCH;NITROGEN;MOLECULES;IODINE;PREDISSOCIATION;FEMTOCHEMISTRY