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Journal of Chemical Physics, Vol.105, No.13, 5647-5650, 1996
Nonadiabatic Wave-Packet Dynamics - Predissociation of IBr
We present results of fs pump-probe experiments on the predissociation dynamics of the IBr B-state, as a model of nonadiabatic wave packet dynamics on coupled potential energy curves. The observations reflect the complicated wave packet motion on the coupled potentials and oscillatory behavior of the decay rates as a function of excitation energy.