The counter-diffusion of aromatic compounds such as coronene and tetra-phenylporphine by injection of acetone or tetra-phenylporphine solution was studied on aluminas and silica-alumina used widely as catalysts support. The counter-diffusivity was determined from simulation results by using the counter-diffusion model employing ideal adsorbed solution theory. The counter-diffusivities of aromatic compounds in the catalyst supports were ranged in ∼10^-15 m²/sec in the desorption process by the injection of excess acetone. In the counter-diffusion process with tetra-phenylporphine solution which have similar concentration with adsorption solution, the counter-diffusivities of coronene were also ∼10^-15 m²/sec, and that of tetra-phenylporphine into pores were determined as ∼10^-11 m²/sec. The counter-diffusivities of coronene desobed from the adsorbent were significantly redyced in comparison with the effective diffusivities when there is counter-diffusion flux. The values mainly depended on the existence of counter-diffusion flux, but not concerned with the species and amount of desorbates.