Oil palm tree residues are a rich biomass resource in Malaysia, and it is therefore very important that they be utilized for more beneficial purposes, particularly in the context of the development of biofuels. This paper described the possibility of utilizing oil palm tree residues as biofuels by producing bin-oil and bin-char via pyrolysis. The process was performed in a fixed-bed reactor at a temperature of 500 C, a nitrogen flow rate of 2 L/min and a reaction time of 60 min. The physical and chemical properties of the products, which are important for biofuel testing, were then characterized. The results showed that the yields of the bio-oil and bin-char obtained from different residues varied within the ranges of 16.58-43.50 wt% and 28.63-36.75 wt%, respectively. The variations in the yields resulted from differences in the relative amounts of cellulose, hemicellulose, lignin, volatiles, fixed carbon, and ash in the samples. The energy density of the bio-char was found to be higher than that of the bio-oil. The highest energy density of the bio-char was obtained from a palm leaf sample (23.32 MJ/kg), while that of the bin-oil was obtained from a frond sample (15.41 MJ/kg). (C) 2013 Elsevier Ltd. All rights reserved.