Fluid Phase Equilibria, Vol.333, 13-17, 2012
Solubilities of D-xylose in water plus (acetic acid or propionic acid) mixtures at atmospheric pressure and different temperatures
Using dynamic method and the laser monitoring observation technique, the solubility of D-xylose in water+acetic acid, and water+propionic acid was measured over the temperature range (296.65-325.45)K at atmospheric pressure. The solubility of D-xylose in the mixtures of water+acetic acid, and water+propionic acid was found to increase with increasing temperature and decrease with increasing volume fractions of acetic acid, and propionic acid in aqueous solution. The experimental data were correlated by using the Apelblat equation, the lambda h equation and the ideal equation. The results showed that these three models agreed well with the experimental data, and the Apelblat equation was found to regress the solubility data better than the other two models. The standard enthalpy, standard entropy, and Gibbs free energy change of solution of D-xylose were calculated from the solubility data by using the Apelblat model. (C) 2012 Elsevier B.V. All rights reserved.
Keywords:D-Xylose;Solid-liquid equilibrium;Solubility;The standard enthalpy;The standard entropy;The standard Gibbs energy