The vapor pressure of the pure component of methyl phenyl carbonate (MPC) was measured at temperatures ranging from 378 K to 488 K. The experimental vapor pressures could be fit well with a three-parameter Antoine equation. Isobaric vapor-liquid equilibria for binary systems (MPC+ methanol and MPC+ dimethyl carbonate) were determined using a dynamic method at 101.3 kPa. They were correlated with Wilson, NRTL and UNIQUAC models. In addition, excess molar volumes (V-E) and deviations in molar refractivity (Delta R) at 298.15 K were recorded for the same binary systems using a digital vibrating tube densitometer and a precision digital refractometer. The V-E and Delta R data were in good agreement with the predictions of the Redlich-Kister equation. (C) 2013 Elsevier B.V. All rights reserved.