The present study is focused on the determination of the solubilization capacity and conductance behavior of mixed microemulsions [AOT/Brij-56 or Brij-58 or Brij-76 or TX-100 or Tween-80/Hp or Dc or IPM/water] in presence of ionic liquids (ILs) of different chemical structures and physicochemical properties [viz. bmimCl, hmimCl, bmimBF(4) and BzmimCl] at different compositions (X-nonionic =0, 0.1) at fixed surfactant concentration and temperature. Synergism in solubilization capacity has been evidenced in c presence of ILs. All these systems exhibit volume-induced percolation of conductance. The maximum solubilization capacity (omega(0,max)), [IL](max) (concentration of ILs at which synergism occurs) and volume-induced percolation threshold (omega(p)) have been found to influence by alkyl side-chain length, anion and polarity of ILs, and polar head group, hydrophobic moiety and content of nonionic surfactant and type of oils. Different solubilization sites of bmimCl and hmimCl have been proposed. ILs have been found to be more efficient additives than NaCl in respect of enhancing omega(0,max) with less [IL](max) and reducing omega(p). The microstructure of AOT and AOT/Brij-56 systems at different X-nonionic (= 0, 0.1) has been determined by DLS and FTIR measurements in absence and presence of ILs. Droplet diameter (d(h)) decreases and relative population of bound water increases with increase in [IL]. An attempt has been made to correlate the solubilization capacity in presence of ILs with percolation of conductance vis-A-vis droplet dimensions and the states of confined water to underline mechanism of solubilization phenomenon in these systems. (C) 2013 Elsevier B.V. All rights reserved.