This work focuses on modeling and experimental investigation of temperature dependent interfacial properties of binary DMF/n-alkane (C7, C10, C12) mixtures. The systems consisting of solvents with very different polarity show azeotropic behavior. New experimental vapor-liquid and liquid-liquid interfacial tension data are provided between 298.15 and 328.15 K using the drop volume method. The Perturbed Chain Polar Statistical Associating Fluid Theory (PCP-SAFT) equation of state was combined with the Density Gradient Theory (DGT) to calculate phase equilibria and interfacial properties. Modeling results are in good agreement with the corresponding experimental data. Thereby, the binary parameter beta(y) within the DGT framework does not equal one. Investigating density and concentration profiles in the interface revealed characteristic trends which are related to the azeotropic behavior of the mixtures. (C) 2013 Elsevier B.V. All rights reserved.