Journal of Chemical Physics, Vol.106, No.2, 605-609, 1997
Coupled Q-Oscillators as a Model for Vibrations of Polyatomic-Molecules
The system of two Q-deformed oscillators coupled so that the total Hamiltonian has the su(Q)(2) symmetry is proved to be equivalent, to lowest order approximation, to a system of two identical Morse oscillators coupled by the cross-anharmonicity usually used empirically in describing vibrational spectra of triatomic molecules. The symmetry also imposes a connection between the self-anharmonicity of the Morse oscillators and the cross-anharmonicity strength, which can be removed by replacing the Q-oscillators by deformed anharmonic oscillators. The generalization to n oscillators is straightforward. The applicability of the formalism to highly symmetric polyatomic molecules is discussed.
Keywords:ALGEBRAIC APPROACH;ANHARMONIC-OSCILLATORS;DEFORMED OSCILLATOR;DIATOMIC-MOLECULES;ABA TRIATOMICS;VIBRON MODEL;SPECTRA;SPECTROSCOPY;DYNAMICS;BENZENE