Coal of three kinds was burned in an oxygen-enriched atmosphere using a twin-fluidized bed solid circulation system under conditions of the Calcium Looping Process. This twin-fluidized bed system comprised a fast bed regenerator (calciner), into which fuel and oxygen-enriched gas were fed, and a bubbling bed absorber (carbonator), into which air was fed. Inert quartz sand was used as the bed material to evaluate the coal combustion behavior, including char transportation from regenerator to absorber and formation of CO and CO2 there. First, the circulation rate and the residence time of solids in the regenerator (calciner) were measured to determine the suitable operation conditions. The effect of gas feed staging to the regenerator on the solid residence time was evaluated. By reducing the ratio of the primary gas feed rate to total gas feed rate to 0.5, average solid residence time of about 40 s was attained. Under this gas-feed condition, coal combustion experiments were conducted. Effects of volatile matter content of coal on CO and CO2 formation in the absorber and NOx emissions from the regenerator were investigated. High-volatile matter coal was found to be favorable to reduce CO and CO2 formation in the absorber, but conversion of the fuel-N to NOx of high-volatile matter coal was higher than that from low-volatile coal. (C) 2013 Elsevier Ltd. All rights reserved.