면섬유에 대한 폴리옥시에틸렌 알킬 인산에스테르의 정련효과

하윤식; 곽경도; 장윤호

Journal of the Korean Industrial and Engineering Chemistry, Vol.10, No.7, 974-978, November, 1999

Export Citation

면섬유에 대한 폴리옥시에틸렌 알킬 인산에스테르의 정련효과

Scouring Effect of PAPE(Polyoxyethylene Alkyl Phosphoric Ester) on Cotton Fibres

하윤식, 곽경도, 장윤호

초록

면섬유에 대한 정련제로서 NP-7(polyoxyethylene(7) nonylphenyl ether) 및 TDA-7((polyoxyethylene(7) tridecyl ether)을 인산에스테르화 반응시켜 PAPE(sodium polyoxyethylene alkyl phosphoric ester)형 음이온 계면활성제인 sodium polyoxyethylene(7) nonylphenyl phosphoric ester(CPB-1)와 sodium polyoxyethylene(7) tridecyl phosphoric ester(CPB-2)를 각각 합성하였다. 합성한 CPB-1과 CPB-2를 기존의 상용제품인 Ultravon GP(GP)와 각 기능별로 성능을 비교하였다. 그 결과 상온 및 100^oC에서의 억포 및 파포력이 CPB-2 > CPB-1 > GP의 순으로 CPB-2의 기포가 가장 적었고, 또한 가장 빨리 파포되어졌다. 증류수에서의 침윤효과는 CPB-1 > GP > CPB-2의 순으로 나타났으나, 실제 일반 정련에서 많이 사용하는 1.2 wt % NaOH 수용액에서의 침윤효과는 전반적으로 CPB-2가 가장 우수한 것으로 나타났다. 섬유가공시의 정련조건인 알카리 상태에서의 안정성은 CPB-2 >=CPB-1>GP의 순으로 나타났으며, 재흡수력 실험결과 CPB-2 > CPB-1 > GP의 순으로 CPB-2의 정련력이 가장 우수한 것으로 나타났다.

This study was concerned with the scouring effect of anionic surfactants, PAPE(sodium polyoxyethylene alkyl phosphoric ester) for cotton fibres. Sodium polyoxyethylene(7) nonylphenyl phosphoric ester(CPB-1) and the sodium polyoxyethylene(7) tridecyl phosphoric ester(CPB-2) were synthesized by the phosphoric esterification reaction from NP-7(polyoxyethylene(7) nonylphenyl ether) and TDA-7(polyoxyethylene(7) tridecyl ether) as scouring agents. Defoaming ability, fibre wetting time and absorbency rate of scouring agents were investigated. Being compared with the conventional scouring agent(Ultravon GP; Ciba-guyge Co.), CPB-1 and CPB-2 showed a higher defoaming ability in the cotton scouring process at room temperature. And CPB-1 has a higher wetting effect than the agents, CPB-2 or GP in distilled water bath but CPB-2 showed more scouring effect in 1.2 wt % NaOH solution bath.

Keywords:scouring agent;phosphoric ester;wetting effect;anionic surfactant

[References]

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BeigelC, Barriuso E, Calvet R, Pesticide Sci., 54, 52 (1998)
Lundsten G, Backlund S, J. Colloid Interface Sci., 169(2), 408 (1995)
Austad T, Matre B, Milter J, Saevareid A, Oyno L, Colloids Surf., 137, 117 (1998)
Nakano A, Tateishi K, Bull. Chem. Soc. Jpn., 70, 2943 (1997)
Shiloach A, Blankschtein D, Langmuir, 14(7), 1618 (1998)
Roy D, Kommalapati RR, Mandva SS, Valsalaj KT, Constant WD, Environ. Sci. Technol., 31, 670 (1997)
Lewin M, Sello SB, Handbook of Fiber Science and Technology: Vol. I, Marcel Dekker, Inc., New York, 113 (1983)
Hochwalt CA, Lum JH, Malowan JE, Dyer CP, Ind. Eng. Chem., 34, 20 (1942)
Cooper RS, J. Am. Oil Chem. Soc., 40, 642 (1963)
Maurer EW, Stirton AJ, Ault WC, Weil JK, J. Am. Oil Chem. Soc., 41, 205 (1964)
Cooper RS, Urfer AD, J. Am. Oil Chem. Soc., 41, 337 (1964)
이상순, 신계면활성제, 도서출판 세화, 서울, 344 (1995)
Fujimoto T, New Introduction to Surface Active Agents, Sanyo Chemical Industries, Ltd., Kyoto, 161 (1985)
Linfield WM, Surfactant Science Series vol. 7, Marcel Dekker, Inc., New York, 509 (1987)
SANDOZ Co., TM Prescription of Sandoz, SANDOZ Co. (1989)
Fujimoto T, New Introduction to Surface Active Agents, Sanyo Chemical Industries, Ltd., Kyoto, 173 (1985)

[1] 西一郞, 今井恰知郞, 笠井正威, 界面活性劑便覽, 産業圖書株式會社版, 東京, 432 (1979)

[2] BeigelC, Barriuso E, Calvet R, Pesticide Sci., 54, 52 (1998)

[3] Lundsten G, Backlund S, J. Colloid Interface Sci., 169(2), 408 (1995)

[4] Austad T, Matre B, Milter J, Saevareid A, Oyno L, Colloids Surf., 137, 117 (1998)

[5] Nakano A, Tateishi K, Bull. Chem. Soc. Jpn., 70, 2943 (1997)

[6] Shiloach A, Blankschtein D, Langmuir, 14(7), 1618 (1998)

[7] Roy D, Kommalapati RR, Mandva SS, Valsalaj KT, Constant WD, Environ. Sci. Technol., 31, 670 (1997)

[8] Lewin M, Sello SB, Handbook of Fiber Science and Technology: Vol. I, Marcel Dekker, Inc., New York, 113 (1983)

[9] Hochwalt CA, Lum JH, Malowan JE, Dyer CP, Ind. Eng. Chem., 34, 20 (1942)

[10] Cooper RS, J. Am. Oil Chem. Soc., 40, 642 (1963)

[11] Maurer EW, Stirton AJ, Ault WC, Weil JK, J. Am. Oil Chem. Soc., 41, 205 (1964)

[12] Cooper RS, Urfer AD, J. Am. Oil Chem. Soc., 41, 337 (1964)

[13] 이상순, 신계면활성제, 도서출판 세화, 서울, 344 (1995)

[14] Fujimoto T, New Introduction to Surface Active Agents, Sanyo Chemical Industries, Ltd., Kyoto, 161 (1985)

[15] Linfield WM, Surfactant Science Series vol. 7, Marcel Dekker, Inc., New York, 509 (1987)

[16] SANDOZ Co., TM Prescription of Sandoz, SANDOZ Co. (1989)

[17] Fujimoto T, New Introduction to Surface Active Agents, Sanyo Chemical Industries, Ltd., Kyoto, 173 (1985)