Journal of Chemical Physics, Vol.106, No.11, 4806-4809, 1997
Effect of Symmetry-Breaking on Vibrational Coherence Transfer in Impulsive Photolysis of Trihalide Ions
Initial breaking of centrosymmetry is demonstrated to enhance transfer of vibrational coherence to products in impulsive photodissociation of trihalide ions in solution.
Keywords:STIMULATED RAMAN-SCATTERING;ULTRAFAST PHOTODISSOCIATION;DYNAMICS;RELAXATION;ETHANOL;PHOTOCHEMISTRY;SIMULATION;SOLVENT;MOTION;I-3(-)