Prior research into the effect of convection on steady-state mass transfer from a spherical particle embedded in a porous medium has used the Darcy model to describe the flow. However, a limitation of the Darcy model is that it does not account for viscous effects near boundaries. Brinkman modified the Darcy model to include these effects by introducing an extra viscous term. Here we investigate the impact of this extra viscous term on the steady-state mass transfer from a sphere at low Peclet number, Pe << 1. We use singular perturbation techniques to find the approximate asymptotic solution for the concentration profile. Mass-release from the surface of the sphere is described by a Robin boundary condition, which represents a first-order chemical reaction. We find that a larger Brinkman viscous boundary layer renders mass transport by convection less effective, and reduces the asymmetry in the pen-sphere concentration profiles. We provide simple analytical expressions that can be used to calculate the concentration profiles, as well as the local and average Sherwood numbers; and comparison to numerical simulations verifies the order of magnitude of the error in the asymptotic expansions. In the appropriate limits, the asymptotic results agree with solutions previously obtained for Stokes and Darcy flow. The solution for Darcy flow with a Robin boundary condition has not been considered previously in the literature and is a new result. Whilst the article has been formulated in terms of mass transfer, the analysis is also applicable to heat transfer, with concentration replaced by temperature and the Sherwood number by the Nusselt number. (C) 2013 Elsevier Ltd. All rights reserved.