화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.32, No.10-11, 1421-1428, 2007
Reactor modeling to simulate catalytic partial oxidation and steam reforming of methane. Comparison of temperature profiles and strategies for hot spot minimization
Catalytic partial oxidation (CPO) reactions of methane in the presence of steam (low temperature CPO, LTCPO) over a noble metal catalyst were investigated. A quasi-homogeneous one-diniensional model was developed in order to model a lab-scale fixed-bed reactor to produce syngas. These model calculations can contribute to the optimization of the process with respect to the formation of important hot spots (Delta T >= 130 degrees). These useful data c in enable the model development in order to study the influence of the space velocity, product composition and other variables. Furthermore. a feed splitting Study was performed. In the heat balance an overall heat transport term was included to account for small heat losses/gains along the reactor. The agreement between Simulations and the degree of detail in the model is appropriate for the amount and kind of experimental data available. Thus, this model can also assist in a pilot reactor design, materials and further scale-up. (C) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.