For clean utilization of coal, enhanced gasification by in situ CO2 capture has the advantage that hydrogen production efficiency is increased while no energy is required for CO2 separation. The unmixed fuel process uses a sorbent material as CO2 carrier and consists of three coupled reactors: a coal gasifier where CO2 is captured generating a H-2-rich gas that can be utilized in fuel cells, a sorbent regenerator where CO2 is released by sorbent calcination and it is ready for capture and a reactor to oxidize the oxygen transfer material which produces a high temperature/pressure vitiated air. This technology has the potential to eliminate the need for the air separation unit using an oxygen transfer material. Reactors' temperatures range from 750 degrees C to 1550 degrees C and the process operates at pressure around 7.0 bar. This paper presents a global thermodynamic model of the fuel processing concept for hydrogen production and CO2 capture combined with fuel and residual heat usage. Hydrogen is directly fed to a solid oxide fuel cell and exhaust streams are used in a gas turbine expander and in a heat recovery steam generator. This paper analyzes the influence of steam to carbon ratio in gasifier and regeneration reactor, pressure of the system, temperature for oxygen transfer material oxidation, purge percentage in calciner, average sorbent activity and oxidant utilization in fuel cell. Electrical efficiency up to 73% is reached under optimal conditions and CO2 capture efficiencies near 96% ensure a good performance for GHG's climate change mitigation targets. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.