The electrolytic hydrogen evolution reaction (HER) on platinum coated nanoporous gold film (PtNPGF) electrode is demonstrated. The deposition of platinum occurred as a spontaneous redox process in which a copper layer, obtained by underpotential deposition, was oxidized by platinum ions, which were reduced and simultaneously deposited. The present method could provide a very low Pt-loading electrode and the results demonstrated that ultra thin Pt coating effected efficiently and behaved as the nanostructured Pt for electrocatalytic hydrogen evolution reaction. The loading of Pt was calculated as 4.2 x 10(-3) mu g cm(-2) for PtNPGF electrode. The current density at -0.4 V and -0.8 V vs. Ag/AgCl was as high as 0.66 A mu g(-1) Pt and 3 A mu g(-1) Pt, respectively and the j(o) was evaluated as 0.03 mA cm(-2) or 8 mA mu g(-1) Pt. The results indicated that increasing electrode area had no catalytic effect, but the nanostructure nature of as-fabricated electrode and submonolayer deposition of copper resulted in electrocatalytic activity for PtNPGF electrode. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.