Journal of Chemical Physics, Vol.107, No.4, 1106-1114, 1997
Infrared-Spectroscopy of the C-H Stretching Modes of Partially F-Substituted Benzenes .3. The First Overtone of Fluorobenzene
In this article we report the study of the first overtone of fluorobenzene (C6H5F) in the wave number range from about 5900 to 6100 cm(-1). The absorption spectrum has been measured with both a low-temperature opto-acoustic cell and a supersonic-beam opto-thermal spectrometer. A theoretical description of the observed, high-resolution spectrum is given in the framework of the one-dimensional algebraic model, inclusive of a complete set of Fermi (anharmonic) interactions.
Keywords:VIBRATIONAL-ENERGY-TRANSFER;INTRAMOLECULAR DYNAMICS;QUANTUM DYNAMICS;POLYATOMIC-MOLECULES;LOCAL MODES;PARA-DIFLUOROBENZENE;ALGEBRAIC MODEL;RELAXATION;SPECTRA;CH(V=3)