The chemical compatibility, thermal expansion and electrochemical property measurements of the SrCo0.8Fe0.2O3-delta (SCF)-La0.45Ce0.55O2-delta (LDC) composite cathodes for solid oxide fuel cells (SOFCs) were investigated by X-ray diffraction (XRD), thermal expansion coefficients (TECs) and cathodic polarization measurements together with electrochemical impedance spectroscopy (EIS). The results indicated that LDC had good chemical compatibility with SCF and La0.9Sr0.1Ga0.8Mg0.2O3-delta (LSGM), and the addition of LDC to SCF markedly reduced the polarization resistance. When the content of LDC reached 50 wt%, the SCF50 cathode showed the best electrochemical performance, with a cathodic over-potential of 0.1 V at the current density of 1102.0 mA cm(-2), together with a polarization resistance of 0.149 Omega cm(2) at 800 degrees C. The improved electrochemical performance was attributed to the expansion of the electrochemical reaction region into the electrode, and offering an easier path for the oxygen ion transport. Furthermore, the SCF LDC composite cathodes match better with the LSGM electrolyte. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.