Destabilization of LiBH4 by addition of metal hydrides or borohydrides is a powerful strategy to develop new promising hydrogen storage systems. In this study, we compare the destabilization behavior of the LiBH4 by addition of MH2 (M = La, Ce). A notable improvement in the hydrogen desorption temperature, the rate and the weight percentage of hydrogen released is observed for LiBH4-MH2 with respect to LiBH4. Formation of LaB6 and CeB6 after dehydriding of the composites is proved by PXRD. Remarkable hydrogen storage reversibility of LiBH4-MH2 composites is confirmed under moderate conditions: 400 degrees C and 6.0 MPa of hydrogen pressure for 4 h without catalyst. The LiBH4-LaH2 composite exhibits improved hydrogen desorption performance compared with LiBH4-CeH2 composite, but the hydrogen storage reversibility is inferior. Notably, the LiBH4-CeH2 nanocomposite produced by in situ formation of CeH2 from Ce(BH4)(3)-LiH displays excellent hydrogen storage properties. The addition of ZrCl4 as a catalyst improves dehydriding kinetics. The mechanism underlying the enhancement in the LiBH4-MH2 composites is also discussed. Our study is the first work about reversible hydrogen storage in LiBH4-LaH2. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.