화학공학소재연구정보센터
Journal of Chemical Physics, Vol.107, No.6, 1759-1764, 1997
Density-Dependence of the Conduction-Band Minimum in Fluid Krypton and Xenon from Field-Ionization of (CH3)(2)S
The ionization potential distribution of (CH3)(2)S doped in fluid krypton and xenon has been determined by means of field ionization in wide density ranges. These distributions are simulated by convoluting the field spectrum of pure (CH3)(2)S With the calculated polarization energy distribution of the dopant ion in the media. The density dependence of the conduction-band energy of excess electrons (V-0) in the fluids is obtained from the energy shift between the experimental and simulated spectra. The resulting V-0 values are compared with previous experimental results and several theoretical calculations.