A numerical model was developed for the evaluation of adsorbent based hydrogen storage systems. The model utilizes commercial software and simultaneously solves the conservation equations for heat, mass and momentum together with the equations for the adsorbent thermodynamics. Conservation equations were derived for a general adsorbent bed-storage vessel configuration and the adsorbent thermodynamics were a modified form of the Dubinin-Astakhov model. The solver was the Comsol (TM) Multiphysics software. Real gas thermodynamic properties for hydrogen were used in the calculations. Model predictions were compared to data for charging an activated carbon based system. Applications of the model were made for charging of MOP-5 (TM). and MaxSorb (TM) based systems that employ flow-through cooling as a means for controlling the adsorbent temperature during charging. In addition, the model was used to evaluate the contribution of pressure work to the total energy released during charging. It was found that flow-through cooling has the potential to be an effective means for heat removal and that the contribution of pressure work can be significant, depending on the type of adsorbent and the charging procedure. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.