Block-type cation-exchange membranes (CEMs) have been prepared by blending poly(vinyl alcohol) (PVA) and the polyanion poly(vinyl alcohol-b-styrene sulfonic acid) at various molar percentages of cation-exchange groups to vinyl alcohol groups, C-pa, and by cross-linking the PVA chains with glutaraldehyde (GA) solution at various GA concentrations, C-GA. The characteristics of the block-type CEMs were compared with random-type CEMs prepared in a previous study from the random copolymer, poly(vinyl alcohol-co-2-acrylamido-2-methylpropane sulfonic acid). At equal molar percentages of the cation-exchange groups, the water content of the block-type CEMs was less than that of the random-type CEMs. The charge density of the block-type CEMs increased with increasing C-pa and reached a maximum value. Further, the maximum value of the charge density increased with increasing C-GA. The maximum charge density value of 1.3 mol/dm(3) was obtained for the block-type CEM with C-pa = 3.1 mol% and C-GA= 0.10 vol.%, which is almost two thirds of the value of a commercially available CEM [CMX: ASTOM Corp. Japan]. A comparison of the block-type and random-type CEMs with almost the same membrane resistance showed that the block-type CEMs had higher dynamic transport numbers than the random-type ones. The dynamic transport number and membrane resistance of the block-type CEM with C-pa = 4.0 mol% and C-GA = 0.10 vol.% were 0.96 and 4.9 Omega cm(2), respectively. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.