International Journal of Hydrogen Energy, Vol.37, No.9, 8087-8094, 2012
Improved oxidation resistance of ferritic steels with LSM coating for high temperature electrochemical applications
The effect of single layer La0.85Sr0.15MnO3-delta (LSM) coatings on high temperature oxidation behaviour of four commercial chromia-forming steels, Crofer 22 APU, Crofer 22 H, E-Brite and AL 29-4C, is studied. The samples were oxidized for 140-1000 h at 1123 K in flowing simulated ambient air (air + 1% H2O) and oxygen and corrosion kinetics monitored by mass increase of the materials over time. The oxide scale microstructure and chemical composition are investigated by scanning electron microscopy/energy-dispersive spectroscopy. The kinetic data obey a parabolic rate law. The results show that the LSM coating acts as an oxygen transport barrier that can significantly reduce the corrosion rate. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.