International Journal of Hydrogen Energy, Vol.37, No.15, 11474-11486, 2012
Hydrogen diffusion and hydrogen influenced critical stress intensity in an API X70 pipeline steel welded joint - Experiments and FE simulations
An API X70 pipeline steel has been investigated with respect to hydrogen diffusion and fracture mechanics properties. A finite element cohesive element approach has been applied to simulate the onset of hydrogen-induced fracture. Base metal, weld simulated heat affected zone and weld metal have been investigated. The electrochemical permeation technique was used to study hydrogen diffusion properties, while in situ fracture mechanics testing was performed in order to establish the hydrogen influenced threshold stress intensity. The average effective diffusion coefficient at room temperature was 7.60 x 10(-11) m(2)/s for the base metal, 4.01 x 10(-11) m(2)/s for weld metal and 1.26 x 10(-11) m(2)/s for the weld simulated heat affected zone. Hydrogen susceptibility was proved to be pronounced for the heat affected zone samples. Fracture toughness samples failed at a net section stress level of 0.65 times the yield strength; whereas the base metal samples did not fail at net section stresses lower than the ultimate tensile strength. The initial cohesive parameters which best fitted the experimental results were sigma(c) = 1500 MPa (3.1.sigma(y)) for the base metal, sigma(c) = 1800 MPa (3.0.sigma(y)) for weld metal and sigma(c) = 1840 MPa (2.3.sigma(y)) for heat affected zone. Threshold stress intensities K-lc,K-HE were in the range 143-149 MPa root m. Copyright (c) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Keywords:Hydrogen embrittlement;Pipeline steel;Welding;Hydrogen diffusion;Cohesive zone modelling;Fracture toughness