The research of advanced and green energy is getting more and more attention because the status quo of the energy shortage and the environment pollution is worse and worse, lithium-air batteries are attracting considerable interest for their high theoretical specific energy and pollution-free. Nevertheless their performance is restricted by many factors, for instance the transfer tunnel for the oxygen is blocked by the discharge products and then the discharge is over ahead of time. In this paper we had prepared the air electrode with double-layer structure which is usually used in proton exchange membrane fuel cell (PEMFC) to increase the discharge capacity, the discharge special capacity of the air electrode could reach 6587 mAh/g of carbon at the rate of 0.15 mA/cm(2). Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.