In order to increase the hydrogen storage capacity of Mg-based materials, a mixture with a composition of 2LiBH(4) + MgF2 and LiBH4, which has a hydrogen storage capacity of 18.4 wt%, were added to MgH2. Ti isopropoxide was also added to MgH2 as a catalyst. A MgH2 composite with a composition of 40 wt%MgH2 + 25 wt%LiBH4 + 30 wt% (2LiBH(4) + MgF2) + 5 wt%Ti isopropoxide (corresponding to 40 wt%MgH2 + 37 wt% LiBH4 + 18 wt%MgF2 + 5 wt%Ti isopropoxide) was prepared by reactive mechanical grinding. The hydrogen storage properties of the sample were then examined. Hydrogen content vs. desorption time curves for consecutive 1st desorptions of 40 wt%MgH2 + 37 wt %LiBH4 + 18 wt%MgF2 + 5 wt%Ti isopropoxide from room temperature to 823 K showed that the total desorbed hydrogen quantity for consecutive 1st desorptions was 8.30 wt%. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.