International Journal of Hydrogen Energy, Vol.39, No.5, 2279-2285, 2014
Performance and degradation of metal-supported solid oxide fuel cells with impregnated electrodes
Metal-supported solid oxide fuel cells (MS-SOFCs) containing porous 430L stainless steel supports, YSZ electrolytes and porous YSZ cathode backbones are fabricated by tape casting, laminating and co-firing in a reducing atmosphere. Nano-scale Ni and La0.6Sr0.4Fe0.9Sc0.1O3-delta,5 (LSFSc) coatings are impregnated onto the internal surfaces of porous 430L and YSZ, acting as the anode and the cathode catalysts, respectively. The resulting MS-SOFCs exhibit maximum power densities of 193, 418, 636 and 907 mW cm(-2) at 650, 700, 750 and 800 degrees C, respectively. Nevertheless, a continuous degradation in the fuel cell performance is observed at 650 degrees C and 0.7 V during a 200-h durability measurement. Possible degradation mechanisms were discussed in detail. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.