Effects of sodium salts on reduction roasting and Fe-P separation of high-phosphorus oolitic hematite ore were studied in the process of coal-based direct reduction followed by wet magnetic separation. Various parameters, including reducing temperature and time, type and dosage of sodium salts, grinding fineness of magnetic separation feed and magnetic field intensity were investigated. The results of reduction and Fe-P magnetic separation are significantly improved by the addition of sodium sulfate and borax, in comparison with those in the absence of additives. A magnetic concentrate with total iron grade of 92.7% and phosphorus content of 0.09% was obtained from an oolitic hematite ore containing 48.96% iron and 1.61% phosphorus when reduced in the presence of 7.5% sodium sulfate and 1.5% borax and wet magnetic separated under the proper conditions. The results of optical microscopy and X-ray diffraction (XRD) analyses of reduced pellet reveal that metallic iron grains exist in sizes of 10-20 mu m and are associated with gangue minerals closely when reduced in the absence of sodium salts. By contrast, the oolitic structure is destroyed and metallic iron grains grow markedly to the mean size of 50 mu m when reduced in the presence of sodium sulfate and borax. Sodium salts are capable of destroying the oolitic structure via reacting with gangues, enhancing the reduction of iron oxide and promoting the growth of metallic iron grains during reduction, which is beneficial for Fe-P separation of the oolitic hematite ore. (C) 2013 Elsevier B.V. All rights reserved.