Journal of Aerosol Science, Vol.37, No.8, 950-966, 2006
Reduction of the condensation/evaporation dynamics for atmospheric aerosols: Theoretical and numerical investigation of hybrid methods
The dynamical behaviour of atmospheric aerosols is characterized by a wide range of timescales, especially due to the fast growth of small particles through condensation/evaporation. The resulting models are particularly stiff and their numerical simulation still remains a challenge. Some techniques based on the assumption of condensation/evaporation equilibrium are usually advocated in order to circumvent these difficulties. The objective of this article is to investigate the different approaches on a theoretical basis. The appropriate framework is the theory of reduction for slow/fast models, for which many tools are already available. The application to aerosol modelling leads to the so-called hybrid methods. We also propose a hierarchy of reduced models and compare some numerical algorithms in a box model simulation for inorganic species. (C) 2005 Elsevier Ltd. All rights reserved.
Keywords:aerosol modelling;particles;GDE;condensation/evaporation;mass transfer;reduction;hybrid models;equilibrium;dynamic;Lagrangian models;bins;bulk;size-resolved models;slow/fast species;lumping;thermodynamic model;isorropia;inorganics