The validity of the one-dimensional (1D) (slenderness) approximation to describing the cone-jet mode of electrospraying is examined by comparing its results with those obtained from the two-dimensional (2D) leaky-dielectric model. This comparison shows that the 1D approach provides accurate predictions for the relevant quantities if the (dimensionless) electrical conductivity and/or the Ohnesorge number are sufficiently high. By using the procedure proposed in Ganan-Calvo, AM. (1999b) (The surface charge in electrospraying: Its nature and its universal scaling laws. Journal of Aerosol Science, 30, 863-872), we show the suitability of the 1D model to precisely "measure" those quantities in an electrospray experiment. Our method combines a super-resolution image processing technique to detect the liquid free surface in the experimental images, and the numerical integration of the 1D model. In this way, the conduction and surface convection contributions to the current intensity, as well as the electric field over the jet' surface, are determined in an experimental realization. (C) 2013 Elsevier Ltd. All rights reserved.