Journal of Chemical Thermodynamics, Vol.47, 397-401, 2012
(Vapour plus liquid) equilibrium data for the binary system of {trifluoroiodomethane (R13I1) + trans-1, 3, 3, 3-tetrafluoropropene (R1234ze (E))} at various temperatures from (258.150 to 298.150) K
(Vapour + liquid) equilibrium (VLE) data for the binary system of {trifluoroiodomethane (R13I1) + trans-1, 3, 3, 3-tetrafluoropropene (R1234ze (E))} were measured by a static-analytic method within the temperature range of (258.150 to 298.150) K. The experimental data were correlated using the Peng-Robinson equation of state (PR EoS) with the Huron-Vidal (HV) mixing rule involving the NRTL activity coefficient model. The results show good agreement with experimental values for the binary system at each temperature point. The maximum average absolute relative deviation of pressure is 0.28%, while the maximum average absolute deviation of vapour phase mole fraction is 0.0025. Obviously azeotropic behaviour can be found for the measured temperature range here. (C) 2011 Elsevier Ltd. All rights reserved.
Keywords:Saturated vapour pressures;(Vapour plus liquid) equilibrium;Trifluoroiodomethane;Trans-1;3;3;3-tetrafluoropropene