Journal of Crystal Growth, Vol.362, 145-148, 2013
Growth of Ce-doped Ba3Gd(BO3)(3) and Sr3Gd(BO3)(3) single crystals by micro-pulling-down method and analysis of luminescence properties
Ce-doped double borates Ba3Gd(BO3)(3) and Sr3Gd(BO3)(3) (Ce:BGB and Ce:SGB, respectively) were grown by the micro-pulling-down method, and the luminescence properties of the crystals were investigated and compared with those of Ce-doped H-Ba3Y(BO3)(3)(Ce:H-BYB) crystals grown by the same method. Transmittance measurements showed the wavelength of absorption band was around 380 nm for all the samples. Emission bands corresponding to the 5d -> 4f transition of Ce3+ were observed at around 425 nm for Ce:BGB and Ce:SGB and at 435 nm for Ce:H-BYB. The photoluminescence decay times of Ce:BGB, Ce:SGB, and Ce:BYB were 29.5 ns, 35.2 ns, and 26.8 ns, respectively. The emission spectra obtained by excitation of Am-241 (an alpha-emitter) revealed that the host luminescence was dominant (at around 315 nm) in BGB and SGB and that a very low-intensity Ce3+ 5d -> 4f luminescence peak appeared at around 430 nm. The relative light yield strength observed under Am-241 excitation was corresponding to <100 and similar to 270 photons/neutron for Ce:BGB and Ce:SGB, respectively, and these values were lower than that of Ce:H-BYB (similar to 400 photons/neutron). (c) 2011 Elsevier B.V. All rights reserved.
Keywords:Micro-pulling-down method;Ba3Gd(BO3)(3);Ba3Y(BO3)(3);Double borate;Sr3Gd(BO3)(3);Ce 5d -> 4f luminescence