Journal of Food Engineering, Vol.114, No.3, 313-322, 2013
Simultaneous and sequential estimation of kinetic parameters in a starch viscosity model
A modified Brookfield viscometer equipped with a data acquisition system was used to study gelatinizing behavior of native corn starch. Data for the dependent variable (continuous torque), and independent variables were collected. The independent variables were time-temperature history, shear history, and temperature, corresponding to the three main regions in a pasting curve. Parameters were estimated simultaneously using both ordinary least squares, and the sequential method. The model fit well as shown by RMSE of approximately 2% of full scale, and relative standard error of all parameters estimated less than 11%. Scaled sensitivity coefficients showed that the most important parameters were time-temperature history, followed by shear history, and the temperature parameter was the least important. This work is the first to show that starch-pasting curve parameters can be estimated simultaneously and sequentially, and can be used to predict pasting curves in other systems (RVA) well. (C) 2012 Elsevier Ltd. All rights reserved.
Keywords:Starch viscosity model;Nonlinear parameter estimation;Pasting curve;Inverse problem;Rapid visco analyzer (RVA);Brookfield viscometer