Journal of Chemical Physics, Vol.112, No.7, 3245-3247, 2000
Hard sphere perturbation theory of dense fluids with singular perturbation
Hard sphere perturbation theories (HSPT) played a significant role in the fundamental understanding of fluids and continues to be a popular method in a wide range of applications. The possibility of difficulty with singular perturbation for some classical soft core model fluids appears to have been overlooked or ignored in the literature. We address this issue in this short note and show by analysis that a region of phase space has been neglected in the standard application of HSPT involving singular perturbation. (C) 2000 American Institute of Physics. [S0021-9606(00)50407-3].
Keywords:LIQUID-METALS