This paper presents a methodology for the calculation of atmospheric stability classes in correlation with wind velocities for six sites of the Greek territory, namely Ellinikon (Athens), Elefsis, Megara, Heraklion, Chania and Patras, based on real data obtained from meteorological observations in these sites and on computations related with their geographic position. In addition to that, a comparison is presented of the atmospheric stability classes produced with online measurements for the Ellinikon (Athens) site with significant coincidence in the results. These calculated values of the meteorological parameters (particularly of atmospheric stability) are most appropriate for uncertainty calculations in quantified risk assessments (QRAs) of hazardous installations sited in the above-mentioned areas, especially when risk and safety-related decisions need to be taken. Consequent results obtained with these parameters are more realistic compared to the "classical" assumption of D5/F2, which leads to significant diversification in the estimation of risk. (C) 2004 Elsevier Ltd. All rights reserved.