Journal of Membrane Science, Vol.409, 75-81, 2012
Functionalization of polysulfone hollow fiber membranes with amphiphilic beta-cyclodextrin and their applications for the removal of endocrine disrupting plasticizer
For the removal of endocrine disrupting chemicals (EDCs), such as di-(2-ethylhexyl) phthalate (DEHP), from drinking water, we prepared beta-cyclodextrin included polysulfone (PSf/CD) hollow fiber membranes. beta-Cyclodextrin (beta-CD) was modified with fatty acid chlorides to produce amphiphilic beta-CDs. PSf/CD hollow fiber membrane was prepared from polysulfone (PSf) dope solution with those amphiphilic beta-CDs by phase inversion process. In the membrane formation process, the amphiphilic beta-CDs migrated to the membrane surfaces via hydrophilic-and hydrophobic-mediated self-assembly. The performances of PSf/CD hollow fiber membranes were measured and the results showed that PSf/CD hollow fiber membranes can effectively remove DEHP from aqueous solutions and provided good water permeability. (C) 2012 Elsevier B.V. All rights reserved.
Keywords:Ultrafiltration;Polysulfone;Endocrine disrupting chemicals;Cyclodextrin;Surface modification;Amphiphilic