In this paper, we fabricated a high strength self-supporting NaA zeolite membrane from a geopolymer membrane through in situ hydrothermal transformation processing. The surface and inner amorphous geopolymer membrane was converted into the zeolite crystal phase after the hydrothermal process was applied, and the volume of the micropores of the hydrothermal sample changed from 0 to 0.049 cc/g after the hydrothermal process. We preliminarily studied the practicability and preparation of a selfsupporting NaA zeolite membrane with a high compressive strength (approximately 57 MPa) for desalination through a pervaporation process. The results showed that the self-supporting NaA zeolite membranes exhibited improved high sodium ion rejection (approximately 99.5%) as the thickness gradually increased to a certain value (about 9.4 mm), and the flux (0.42 kg m(-2) h(-1) at 25 degrees C) gradually increased to 3.86 kg m(-2) h(-1) as the pervaporation temperature increased to 90 degrees C. (c) 2013 Elsevier B.V. All rights reserved.