A high temperature proton-exchange membrane (PEM), polytetrafluoroethylene-poly(ethersulphone)-poly(vinyl pyrrolidone) (PES-PVP/PTFE) composite membranes, was prepared by impregnating PES-PVP solutions into the porous PTFE films to reinforce the mechanical properties thereof. After doping with phosphoric acid (PA), the tensile strength and Young's modulus of PES-PVP/PTFE composite membranes were much higher than those of the PA doped PES-PVP membrane. PA doping level of the composite membrane was positively related to the impregnating degree of PES-PVP into PTFE. In this study, the PES-PVP/PTFE composite membranes with the optimized impregnating degree exhibited a proton conductivity of 0.26 S cm(-1) at 180 degrees C with 560 wt% H3PO4 doped. The high-temperature PEMFCs with PES-PVP/PTFE-5 composite membrane demonstrated a maximum power density of 607 mW cm(-2) at 180 degrees C with H-2/O-2 system. Furthermore, the PES-PVP/PTFE composite membranes show a low H-2 crossover current density in high-temperature PEMFCs. (C) 2014 Elsevier B.V. All rights reserved.