화학공학소재연구정보센터
Journal of Non-Newtonian Fluid Mechanics, Vol.198, 71-77, 2013
High-shear drag reduction of surfactant solutions
Drag reducing surfactants produce micellar structures. Over critical shear stress, the break-up rate of these structures tends to be faster than the formation rate. An excess of counterions raises the critical shear stress, and enhances surfactant drag reduction up to higher shear in turbulent flow. We investigated this high-shear drag reduction for small circular cross-section tubes. The enhancement became saturated when the counterion to surfactant molar concentration ratio was higher than ten. This saturated condition allowed a 30% drag reduction for a wall shear stress of 10(3) Pa (approximately 10(6) s(-1) shear rate) for a 1500 ppm surfactant solution. The frictional drag of the tube flow was dependent on a Reynolds number at low shear and obeyed the friction formulas of a laminar pipe flow and a limiting drag reduction flow. Over critical shear stress, high shear decreased the drag reduction because of break-up of drag reducing micellar structures. This disappearance of the drag reduction was found to be a function of wall shear stress and independent of the tube diameters under saturated counterion-effect conditions. A phenomenological formula was introduced to describe the flow friction for these saturated counterion-effect conditions. (C) 2013 Elsevier B.V. All rights reserved.