Macromolecular Research, Vol.22, No.8, 853-858, August, 2014
The Effect of H2O2/Fe2+ Catalytic Oxidation System on the Morphology, Structure and Properties of Flake-Like Poly(2,3-dimethylaniline)
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In this work, flake-like poly(2,3-dimethylaniline) (P(2,3-DMA)) with enhanced thermal stability and anticorrosive ability was synthesized by in situ polymerization using H2O2/Fe2+ catalytic oxidation system, comparing with traditional oxidant ammonium persulfate (APS) synthetic method. The structure and morphology of the samples were characterized Fourier transform infrared (FTIR) spectra, X-ray diffraction (XRD) and field-emission scanning electron microscope (FESEM). The experimental results demonstrated that using H2O2/Fe2+ catalytic oxidation
system was more inclined to form the two-dimensional P(2,3-DMA) flakes. The enhancement in thermostability and corrosion resistance was attributed to the formation of phenazine-like structures in the polymer chains, which could serve as templates to form the flake-like morphology. In addition, using H2O2/Fe2+ catalytic oxidation system is more environmental friendly than the APS method that can avoid ammonium pollution on aquatic life as well as waters.
- Wan MX, Macromol. Rapid Commun., 30(12), 963 (2009)
- Hao Y, Zhou B, Wang F, Li J, Deng L, Liu YN, Biosens. Bioelectron., 52, 422 (2014)
- Banerjee S, Konwar D, Kumar A, Sens. Actuators B: Chem., 190, 199 (2014)
- Van Tuan C, Tuan MA, Van Hieu N, Trung T, Curr. Appl. Phys., 12(4), 1011 (2012)
- Wang H, Zhu E, Yang J, Zhou P, Sun D, Tang W, J. Phys. Chem. C, 116, 13013 (2012)
- Oyharcabal M, Olinga T, Foulc MP, Lacomme S, Gontier E, Vigneras V, Compos. Sci. Technol., 74, 107 (2013)
- Yeh JM, Liou SJ, Lai CY, Wu PC, Chem. Mater., 13, 1131 (2001)
- Ma L, Fu D, Gan M, Zhang F, Li Z, Li S, J. Appl. Polym. Sci., 130, 4528 (2013)
- Jadhav N, Vetter CA, Gelling VJ, Electrochim. Acta, 102, 28 (2013)
- Kalendova A, Prog. Org. Coat., 46, 324 (2003)
- Siljeg M, Foglar L, Kukucka M, J. Hazard. Mater., 178(1-3), 572 (2010)
- Wang Y, Jing X, Kong J, Synth. Met., 157, 269 (2007)
- Zhang HB, Wang JX, Wang Z, Zhang FB, Wang SC, Macromol. Rapid Commun., 30(18), 1577 (2009)
- Zhu S, Chen X, Gou Y, Zhou Z, Jiang M, Lu J, Hui D, Polym. Adv. Technol., 23, 796 (2012)
- Laslau C, Zujovic Z, Travas-Sejdic J, Prog. Polym. Sci., 35, 1403 (2010)
- Ma L, Huang CQ, Gan MY, J. Appl. Polym. Sci., 127(5), 3699 (2013)
- Chung YC, Park JS, Shin CH, Choi JW, Chun BC, Macromol. Res., 20(1), 66 (2012)
- Kim ES, Kim SH, Lee CH, Macromol. Res., 18(3), 215 (2010)
- Baek S, Ree JJ, Ree M, J. Polym. Sci. A: Polym. Chem., 40(8), 983 (2002)
- Li GC, Zhang CQ, Li YM, Peng HR, Chen KZ, Polymer, 51(9), 1934 (2010)
- Tran HD, Norris I, D'Arcy JM, Tsang H, Wang Y, Mattes BR, Kaner RB, Macromolecules, 41(20), 7405 (2008)
- Li XG, Duan W, Huang MR, Yang YL, J. Polym. Sci. A: Polym. Chem., 39(22), 3989 (2001)
- Tang Q, Sun X, Li Q, Wu J, Lin J, Huang M, Mater. Lett., 63, 540 (2009)
- Song G, Han J, Bo J, Guo R, J. Mater. Sci., 44, 715 (2008)
- Stejskal J, Sapurina I, Trchova M, Prog. Polym. Sci., 35, 1420 (2010)
- Wang H, Lu Y, Synth. Met., 162, 1369 (2012)
- Trchova M, Sedenkova I, Konyushenko EN, Stejskal J, Holler P, Ciric-Marjanovic G, J. Phys. Chem. B, 110(19), 9461 (2006)
- Stejskal J, Sapurina I, Trchova M, Konyushenko EN, Holler P, Polymer, 47(25), 8253 (2006)
- da Silva JEP, de Faria DLA, de Torresi SIC, Temperini MLA, Macromolecules, 33(8), 3077 (2000)
- Lu W, Elsenbaumer RL, Wessling B, Synth. Met., 71, 2163 (1995)
- Wessling B, Synth. Met., 85, 1313 (1997)