화학공학소재연구정보센터
Macromolecular Research, Vol.22, No.8, 895-900, August, 2014
Electrospun Ag-CoF Doped PU Nanofibers: Effective Visible Light Catalyst for Photodegradation of Organic Dyes
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In this study, a novel polyurethane (PU) nanofibrous mat doped with Ag-CoF NPs has been synthesized by electrospinning technique in which the in situ reduction of Ag+ into Ag NPs was achieved by utilizing the reduction ability of N,N-dimethylformamide (DMF), which played dual roles as a solvent and reducing agent. Typically, solgel consisting of CoF/PU and AgNO3 was stirred for 3 h and electrospun. The crystalline structure and uniform distribution of Ag-CoF NPs in/on PU NFs were demonstrated by X-ray diffraction (XRD) and transmission electron microscopy (TEM), respectively. Two organic dyes, MB and RhB, were used to investigate the photocatalytic activity of the nanofibrous mat under visible light irradiation.
  1. Robinson T, McMullan G, Marchant R, Nigam P, Bioresour. Technol., 77(3), 247 (2001)
  2. Qadri S, Ganoe A, Haik Y, J. Hazard. Mater., 169(1-3), 318 (2009)
  3. Wang JL, Xu LJ, Crit. Rev. Environ. Sci. Technol., 42, 251 (2012)
  4. Wu CH, Chang HW, Chern JM, J. Hazard. Mater., 137(1), 336 (2006)
  5. Verma AK, Dash RR, Bhunia P, J. Environ. Manage., 93, 154 (2012)
  6. Leda MSC, Helton JA, Onelia AADS, Creusa MMC, Dyes Pigm., 76, 525 (2008)
  7. Hoffmann MR, Martin ST, Choi WY, Bahnemann DW, Chem. Rev., 95(1), 69 (1995) 
  8. Mo J, Zhang Y, Xu Q, Lamson JJ, Zhao R, Atmos. Environ., 43, 2229 (2009)
  9. Shi Y, Zhou K, Wang B, Jiang S, Qian X, Gui Z, Yuen RKK, Hu Y, J. Mater. Chem., 2, 535 (2014)
  10. Fu YS, Chen HQ, Sun XQ, Wang X, Appl. Catal. B: Environ., 111, 280 (2012)
  11. Yang Q, Choi H, Al-Abed SR, Dionysiou DD, Appl. Catal. B: Environ., 88(3-4), 462 (2009)
  12. Yao YJ, Yang ZH, Zhang DW, Peng WC, Sun HQ, Wang SB, Ind. Eng. Chem. Res., 51(17), 6044 (2012)
  13. Xiong P, Zhu JW, Wang X, Ind. Eng. Chem. Res., 52(48), 17126 (2013)
  14. Li CJ, Wang JN, Wang B, Gong JR, Lin Z, Mater. Res. Bull., 47(2), 333 (2012)
  15. Xiong P, Wang LJ, Sun XQ, Xu BH, Wang X, Ind. Eng. Chem. Res., 52(30), 10105 (2013)
  16. Zhu M, Chen P, Liu M, ACS Nano, 5, 4529 (2011)
  17. Liu R, Wang P, Wang X, Yu H, Yu J, J. Phys. Chem. C, 116, 17721 (2012)
  18. Luo G, Jiang X, Li M, Shen Q, Zhang L, Yu H, ACS Appl. Mater. Interfaces, 5, 2161 (2013)
  19. Han JH, Taylor JD, Kim DS, Kim YS, Kim YT, Cha GS, Nam H, Sens. Actuators B, 123, 384 (2007)
  20. Hains N, Friscic V, Gordos D, Int. J. Cloth Sci. Technol., 15, 250 (2003)
  21. Ge J, Si Y, Fu F, Wang J, Yang J, Cui L, Ding B, Yu J, Sun G, RSC Adv., 3, 2248 (2013)
  22. Wang XF, Ding B, Sun G, Wang MR, Yu JY, Prog. Mater. Sci., 58(8), 1173 (2013)
  23. Lin J, Wang X, Ding B, Yu J, Sun G, Wang M, Crit. Rev. Solid State Mater. Sci., 37, 94 (2012)
  24. Panthi G, Barakat NAM, Khalil KA, Yousef A, Jeon KS, Kim HY, Ceram. Int., 39, 1469 (2013)
  25. Su C, Tong Y, Zhang M, Zhang Y, Shao C, RCS Adv., 13, 3021 (2011)
  26. Panthi G, Barakat NAM, Al-Deyab SS, El-Newehy M, Pandeya DR, Kim HY, J. Appl. Polym. Sci., 127(3), 2025 (2013)
  27. Su C, Ran X, Hu J, Shao C, Environ. Sci. Technol., 47, 11562 (2013)
  28. Jin WJ, Lee HK, Jeong EH, Park WH, Youk JH, Macromol. Rapid Commun., 26(24), 1903 (2005)
  29. Wang N, Raza A, Si Y, Yu JY, Sun G, Ding B, J. Colloid Interface Sci., 398, 240 (2013)
  30. Sheikh FA, Barakat NAM, Kanjwal MA, Chaudhari AA, Jung IH, Lee JH, Kim HY, Macromol. Res., 17(9), 688 (2009)
  31. Su C, Liu L, Zhang M, Zhang Y, Shao C, Cryst. Eng. Commun., 14, 3989 (2012)
  32. Kooti M, Saiahi S, Motamedi H, J. Magn. Magn. Mater., 333, 138 (2013)
  33. Stuart BH, Infrared Spectroscopy: Fundamentals and Applications, John Wiley & Sons, Chichester (2004)
  34. Liu HZ, Zheng SX, Macromol. Rapid Commun., 26(3), 196 (2005)
  35. He T, Zhou Z, Xu W, Cao Y, Shi Z, Pan WP, Compos. Sci. Technol., 70, 1469 (2010)
  36. Jain P, Pradeep T, Biotechnol. Bioeng., 90(1), 59 (2005)
  37. Yu ZQ, Chuang SSC, J. Phys. Chem. C, 111, 13813 (2007)
  38. He Z, Sun C, Yang SG, Ding YC, He H, Wang ZL, J. Hazard. Mater., 162(2-3), 1477 (2009)
  39. Zhou X, Hu C, Hu X, Peng T, Qu J, J. Phys. Chem. C, 114, 2746 (2010)
  40. Christopher P, Xin HL, Linic S, Nat. Chem., 3, 467 (2011)
  41. Yu JG, Dai GP, Huang BB, J. Phys. Chem. C, 113, 16394 (2009)