We report the synthesis and electrochemical performance of one dimensional NiO nanofibers by simple electrospinning technique and subsequently heat treated at 800 C to yield single phase material. After the heat treatment, thickness and crystal size electrospun NiO is found similar to 1 mu m and 100 nm, respectively. The electrospun nanofibers are subjected to various characterizations such as X-ray diffraction with Rietveld refinement, scanning electron microscopy and transmission electron microscopy (TEM). Half-cell assembly is used to evaluate the Li-uptake properties and found maximum reversible capacity of similar to 784 mA h g(-1) at current density of 80 mA g(-1) with operating potential of similar to 1.27 V vs. Li. The test cell rendered good cycleability and exhibits capacity retention of over 75% of reversible capacity after 100 cycles. The conversion mechanism of metallic nanoparticles (Ni-0) are validated though ex-situ TEM measurements. Rate performance studies are also conducted and delivered good cycling properties under such high current studies. (C) 2012 Elsevier B.V. All rights reserved.